Conductive Biohybrid Aerogels
In this research program we are tuning the interactions of nanocellulose and conductive nanomaterials such as silver nanowires, carbon nanotubes and MXenes in colloidal dispersions that can be processed into aerogels with tailored structural and physical properties.
Nanocellulose has unique surface and charge properties that allow these biopolymers to act as dispersant and structure directing agents for a well controlled arrangement of conductive nanomaterials in liquid dispersions. Using directional freezing coupled with ambient, freeze or supercritical drying techniques makes it possible to control the microstrutcture of the resulting biohybrid foams or aerogels. Varying the relative amount and morphology of the nanocellulose and the conductive nanomaterials renders pore walls with controllable mechanical and electrical conductive properties, which translates to the macroscopic materials that can be designed to be e.g. stiff and strong, soft and elastic as well as insulating or highly conductive.
We have explored this rich freedom in changing the structural and physical properties of these ultralight materials to develop materials for pressure sensing, electromagnetic shielding and novel optical elements such as phase shifters, polarizers and absorbers.
This work has been disclosed in numerous scientific publications including highly cited papers in Advanced Science, ACS Nano, Journal of Materials Chemistry A and ACS Nano.
The work has also been widely reported through Empa media releases on the World’s lightest shielding material with following features in Phys.org and Nanowerk.
Sustainable Spray PAckaging
In the “Sustainable Spray Packaging” project we developed circular cellulose-based packaging materials utilizing cellulose recovered from agricultural waste.
Taking inspiration from conventional plastic wrap used to protect cucumbers, in this project agricultural waste products in the form of carrots (or other produce that could not be sold for aesthetic or quality reasons) were used as a source for extracting high quality cellulose fibers that can be used in a formulation as a sprayable protective coating that can be directly applied to the surface of fruits and vegetables. Our labscale tests showed a significantly prolonged shelf life of cucumber of more than 2 weeks on par with the traditional materials while coming completely from renewable resources that would otherwise be wasted.
The project was carried out in collaboration with Lidl Switzerland and was selected as one of the finalists for the Swiss Technology Award 2023 in the Swiss Innovation Forum (SIF). The video showcasing the project and our partners from Lidl for the award ceremony can be seen below.
This work was supported by an Innosuisse Grant (53613.1 IP-EE) and has been disclosed in a patent application and scientific publications in ACS Sustainable Chemistry & Engineering and International Journal of Biological Macromolecules.
The work has also been widely reported through the Empa media release Ecological coating for bananas with a wide coverage in national and international media including NZZ, SRF, BBC and Fast Company.
Green Smart Packaging
In the project “Green Smart Packaging” we are developing green printed sensor tags that can be used to monitor the quality of perishable goods such as food and pharmaceuticals across the logistics chain.
The goal of this project is to realize ultra-low cost simple eco-friendly chipless sensor tags that are read fully automatically without altering existing infrastructure and processes in authentication and logistics, based on our joint expertise in biocompatible and biodegradable materials, sensors, printed electronics and zero power RF systems.
Our focus application is smart packaging of perishable goods, with a key use for pharmaceuticals that have to be kept below 25 °C and below 60% relative humidity. Achieving this in a simple, printed and fully biodegradable sensing tag is the big challenge that GREENsPACK will tackle and solve. Knowledge generated in the project will also be useful for further sensitive products monitoring such as biological samples and organs, for environmental, agriculture and physiological sensing, as well as for transient electronics.
This work is carried out in collaboration with EPFL and CSEM and was supported by the Swiss National Science Foundation Bridge Discovery program (Grant No: 40B2-0_187223/1) and the results have been disclosed in Scientific Reports, Advanced Materials Technologies and a patent application.
More information can be found on the project web page linked here.
Printed paper Batteries
We are developing a new type of eco-friendly energy source on paper-based substrates using nanocellulose as an integral component combined with other environmentally benign materials.
The fabrication is done using scalable printing processes and our devices are targeted for low cost large volume applications within environmental and agricultural sensing, food packaging tracking and sensing and biomedical devices and implants.
The development in this project has been guided by the choice of materials where we have specifically focused on green materials with low environmental impact to design battery systems that can be recycled but also safely degraded in the environment. Two different technologies have been developed one is a fully 3D printed disposable carbon-based supercapacitor and the other is a water activated paper based zinc-air primary battery.
This work was supported by an Empa Internal Research project and the results have been disclosed in Advanced Materials were the supercapacitor work was featured on the journal cover and in Scientific Reports where the article was among the 100 most downloaded overall and the number one most downloaded within materials science for 2022.
The work has also been widely reported through Empa media releases on the biodegradable supercapacitor and the water activated paper battery with following features in Swiss TV SRF 10 vor 10 and in international press including Scientific American and Time Magazine where it was included on the list of “Best Inventions of 2022”.
Ultralight Gold Aerogels
We created a new kind of foam - a three-dimensional mesh of gold - that is a thousand times lighter than conventional gold alloys.
The new gold form is almost impossible to differentiate from conventional gold with the naked eye - the aerogel even has a metallic shine. But in contrast to its conventional form, it is soft and malleable by hand. It consists of 98 parts air and only two parts of solid material. Of this solid material, more than four-fifths are gold and less than one-fifth is milk protein fibrils.
The porous material was created by first heating milk proteins to produce nanometre-fine protein fibres, called amyloid fibrils, which were then placed in a solution of gold salt. The protein fibres then directed the nucleation of gold crystals that were stabilized in an amyloid fibril network.
One of the big challenges to solve in this project was to dry this fine network structure without destroying it. As a first step a gentle protocol to stabilize the liquid material in a gel phase using salt was developed and as air drying causes too much capillary stresses on the structure dyring using supercritical carbon dioxide was used. Since the optical properties of the gold aerogels on the size and shape of the gold particles we showed that if we change the reaction conditions in order that the gold doesn't crystallise into microparticles but rather smaller nanoparticles, it results in a dark-red gold. By this means we can change both the color and the physical (e.g. conductive or catalytic) properties of the material. This means that the material can be used directly as a gold material but also further applications as pressure sensing and catalysis membrane was also demonstrated.
The original work was published in the journal Advanced Materials and widely reported in the press including Daily Mail, Scientific American and USA Today.
Twisted Fibrils
In the project Twisted Fibrils – A Look into their Chiral Liquid Crystal Self-Assembly we investigated the fine nanoscale structures of cellulose and protein nanofibrils and developed new polarized optical microscopy techniques to study their liquid crystal phase behavior.
The resulting fine structural features of both the amyloid and cellulose nanofibrils are intimately linked to their processing conditions and surrounding physical conditions. We found direct evidence of a right-handed chirality on the single fibril level for the cellulose nanofibrils and could also show that the amount of right-handed twisting can be tuned by changing the average charge density on the fibrils where a higher amount of charge results in a higher twisted.
We were also able to show that the sharp discontinuities found along the cellulose nanofibril contours, sometimes called kinks, are a non-native feature in this system. The density of kinks is closely related to the processing conditions for the fibrils and increasing mechanical treatment during fibrillation was found to induce kinks. Using an acid hydrolysis process we were also able to show that the acid induced breakage into smaller cellulose nanocrystals occurs preferentially at positions of kinks.
This work was kindly supported by an ETH Career Seed Grant (SEED-43 16-1) and resulted in several scientific publications including reports in Nature Communications, ACS Nano, Biomacromolecules and Nanoscale.
Nanofiber aerogels
In the project “Nanofiber Aerogels – from a Fundamental Understanding of Structure towards Transparent Flexible Insulation and Functional Hybrids” we investigated the structure-property relationships in cellulose and protein nanofiber gels and aerogels.
The fundamental results of this project helped in advancing our understanding of the classification of nanocellulose gel networks and showed how single nanofibril parameters such as average contour and segment length can be directly linked to elastic properties of the corresponding gel network.
With this fundamental knowledge as a basis a number of functional hybrid aerogels were prepared including cellulose-titanium dioxide porous membranes, prepared by electrostatic assembly ,for flow through photo catalysis and amyloid fibril templated calcium carbonate and silver nanoparticle hybrid systems.
This work was supported by an SNSF Ambizione Fellowship (PZOOP2_168023/1) and the results were reported in numerous scientific publications including Angewandte Chemie, Advanced Functional Materials, Current Opinion in Colloid & Interface Science and Nanoscale.